Sodium Metabisulphite: A Deep Dive into Its Role and Impact

Historical Development

People started making sodium metabisulphite in large batches during the late 19th and early 20th centuries as industries moved toward chemical solutions to solve basic challenges. Textile factories used it to bleach fabrics, making it valuable not just for manufacturers but for ordinary households that bought improved colorfast clothing. My chemistry teacher told stories about how older bread recipes didn’t last very long on the shelf until sodium metabisulphite helped slow the growth of spoilage bacteria. This compound’s story shows how science doesn’t always come from grand inventions—sometimes it’s steady, practical improvements that make life easier. Once its value was clear, saltworks near mineral sources became reliable suppliers, and sodium metabisulphite spread around the globe, quickly building up a reputation among professionals in food, mining, water treatment, and more.

Product Overview

Sodium metabisulphite lands in stores and labs as a white or slightly yellow powder, available in both fine and granular forms. The bag carries a tangy, sulfur smell similar to burning matches—a hint about its origins and uses. Companies put it to work as a preservative and antioxidant, helping fruit, wine, canned goods, and seafood avoid color changes and spoilage. People running water treatment plants, swimming pools, and breweries reach for it often because it saves money and obeys food safety standards. Anyone handling a shipment knows this compound occupies a liminal space: powerful as a chemical tool, but not to be tossed around like table salt, since it brings both opportunity and risk.

Physical & Chemical Properties

Sodium metabisulphite has a molecular formula Na2S2O5 and a molar mass of about 190.1 g/mol. It dissolves easily in water, and its solutions release sulfur dioxide, which acts as a strong reducing agent. The powder draws moisture and should stay dry—otherwise, it loses punch and can cake. My nephew once tried using an old bag in his home-brewed wine and found the results disappointing because it dissolved unevenly. High reactivity with strong acids pumps out acrid SO2; I saw this firsthand in the lab, where even tiny spills caused scrambles to ventilate the room. It doesn’t last long in humid air because it reacts with oxygen and moisture, making known shelf-life and storage a practical necessity.

Technical Specifications & Labeling

Quality control labs demand sodium metabisulphite with a purity above 97% for food and pharmaceutical processes, checked with titration and spectroscopy. Labels state the country of origin, the grade (food, industrial, technical), batch number, net weight, hazard warnings, and safety data. Years ago, missing information led to a headache at our plant—a supplier failed to list a contaminant that caused off-flavors in a product line. Trustworthy brands add shelf-life data, recommended storage conditions, and ingredient traces. Certification from groups like ISO or HACCP helps industries guarantee safety and compliance. It’s not a mystery ingredient—tracking its source and quality means fewer recalls and better consumer confidence.

Preparation Method

Factories make sodium metabisulphite by passing sulfur dioxide gas into a sodium carbonate or sodium hydroxide solution, followed by evaporation and crystallization. Someone pouring the solution sees the white flakes forming as the liquid cools. The right ratio, temperature, and pH deliver the highest yields; old methods resulted in dustier products with more contaminants. Large industrial setups reuse water and gases to cut down on waste and lower costs, showing how even bulk chemicals can shift toward sustainability. The constant search for cleaner and more efficient production matches industry’s broader move to reduce environmental impact.

Chemical Reactions & Modifications

It responds rapidly to acids, releasing sulfur dioxide gas—a tool for winemakers and food packagers fighting microbes. Combine it with oxidizers like chlorine or permanganate, and you see immediate, sometimes violent, reactions. I watched a demonstration where mixing just a gram with bleach produced a cloud that cleared the room. Its reducing action breaks down unwanted color in pulp and textiles, makes metals easier to separate from ore, and cleans up industrial discharge by stripping out residual chlorine. Chemists sometimes modify sodium metabisulphite to tailor its shelf life or reduce its dustiness, making it safer for repeated handling. These reactions highlight why training matters—ignorance about even a teaspoon of this powder can turn a minor mistake into an industrial accident.

Synonyms & Product Names

In grocery aisles and chemical catalogs, sodium metabisulphite goes by names like disodium disulfite, sodium pyrosulfite, and E223. Wine supply stores sometimes call it sodium bisulfite, though chemistry nerds point out the differences. Importers and international users deal with translations in French (metabisulfite de sodium), German (Natriummetabisulfit), and Mandarin (亚硫酸钠), adding to label confusion. Regulatory bodies and consumer groups try to simplify labeling, but legacy naming lingers. This tangle of synonyms matters more than it seems—a wrong label sent to a bakery once caused a batch recall because the staff confused it with similar-sounding stabilizers.

Safety & Operational Standards

Spotting sodium metabisulphite on-site means protective gloves, safety glasses, and sometimes even air filters for sensitive workers. Inhaling dust or SO2 gas leads to coughing, irritation, and asthma-like symptoms; my old supervisor landed in the ER after working near an open bag without a mask. Food regulations cap allowable residues at parts per million, especially since sensitive consumers report headaches, wheezing, or hives from low exposures. OSHA, FDA, and the European Food Safety Authority regularly revise limits and respond quickly to new research. Transporting large quantities follows rules set for hazardous materials: sealed containers, no mixing with acids, posted hazard diamonds. Standard operating procedures in my workplace call for emergency eyewash stations, ready staff, and immediate spill reporting, not because anybody expects failure, but because it’s better to react to the known than scramble during a crisis.

Application Area

This compound serves as a reliable preservative in dried fruit, wine, jams, seafood, and pickles. The food industry finds value in long shelf-life and cost efficiency. Water treatment relies on its ability to remove excess chlorine, while mining operations prefer its reducing power to extract precious metals. The textile and paper industries turn to sodium metabisulphite as a bleaching agent. Photographic processing, leather tanning, and even pharmaceuticals rely on its properties, though quality specifications differ for each use. Much of this wasn’t planned; applications snowballed as new workers found unexpected uses, like a winemaker lowering histamine levels and a chef keeping shellfish fresh for longer market runs. Stories from food safety investigators show that mistakes—using too much, or substituting with the wrong grade—still crop up, but regular audits and better training stop most problems in their tracks.

Research & Development

Laboratories working with sodium metabisulphite push for alternatives that deliver the same effects without allergenic risks. Some teams experiment with blending it with other preservatives, making products safer for sensitive people while keeping microbial control. Green chemists want to deal with leftover waste that contains sulfites, especially after mining or textile operations. Innovation springs up where regulatory approvals lag behind real-life needs; researchers at universities run experiments on how to neutralize or recycle spent sodium metabisulphite. Smaller food startups want to cut back on artificial additives altogether, but the cost of change means the compound sticks around longer than some expect. Every year brings fresh journal publications dissecting its behavior in food, human metabolism, and the environment.

Toxicity Research

Toxicologists track how sodium metabisulphite behaves in the human body, especially among asthma patients and kids. Inhaled dust or vapors push rescue inhaler use higher for some workers—numbers published by health departments keep growers and food processors honest. The compound’s metabolites show up in urine and blood; research pieces draw clear lines between high exposure and acute breathing problems or low-grade chronic cough. Agencies call for more long-term studies in at-risk and vulnerable populations. Research centers using animals have measured reproductive and developmental effects at far higher doses than anyone would reasonably encounter, but those findings guide future reforms and better labeling. Having read FDA summaries, I see strict rules about food and beverage residues shift with pressure from consumer groups. This vigilance only tightens as more families deal with allergies, making transparency and documentation all the more important.

Future Prospects

Industries keep sodium metabisulphite in their toolkit because it keeps cost low and results reliable. Some governments weigh bans or tighter limits as part of food additive overhauls, but businesses push back, citing years of safe use and a lack of affordable substitutes. Research keeps looking for cleaner, safer, and more sustainable options, though transition times appear long. Market forecasts predict demand will rise in Asia and Africa, where cold chain logistics demand strong, accessible preservatives. I see educational campaigns growing in parallel, informing kitchen workers, winemakers, and even school science teachers about safe use and exposure risks. Sustainability conversations push producers toward recycling and green chemistry approaches for both sodium metabisulphite and its waste. If the newest research succeeds, future shelves might hold cleaner alternatives made from plants or fermentation, but that vision still depends on the collective appetite for change across growers, regulators, and consumers all over the world.



What is Sodium Metabisulphite used for?

Why This Chemical Matters

Sodium metabisulphite shows up in more places than most folks realize. The food you eat, the water you drink, photos you develop—this chemical touches ordinary lives daily. Sometimes, people worry when they spot hard-to-pronounce words on food labels. And fair enough: nobody wants mystery chemicals in tonight’s dinner. Still, it helps to know what’s really behind names like sodium metabisulphite.

Food Preservation in the Real World

As a preservative, sodium metabisulphite keeps dried fruits colorful, stops soft drinks from growing bacteria, and helps winemakers protect taste. Without preservatives, foods spoil fast and become unsafe. Dried apricots, for example, stay brightly orange because this chemical blocks reactions that turn them brown and mushy. Clean drinking water also depends on these kinds of agents—at water treatment plants, sodium metabisulphite removes excess chlorine after disinfection, making water taste fresh.

Sulfites, including sodium metabisulphite, have sparked debates over allergies and health. People with asthma or certain sensitivities should pay close attention to labels. The FDA requires that food packages clearly state if sulfites are present when levels might harm sensitive folks. This kind of transparency matters to me as both an eater and a parent. No one likes surprise reactions after a meal. Trust builds when companies follow clear safety rules.

Other Roles You Might Not Expect

Bakeries depend on this compound to help support dough texture. The chemical softens gluten during breadmaking, which allows for consistently fluffy slices. In the wine industry, it stands guard against unwanted bacteria and ensures drinks stay true to flavor profiles. Without sodium metabisulphite, winemakers would struggle to deliver age-old tastes and freshness.

Hospitals and doctors also rely on this chemical to preserve some medicines and lab samples. It helps keep chemicals in stable form until use. Photographers once counted on sodium metabisulphite to keep darkroom chemicals fresh for developing film prints. On the roads, municipal workers add the chemical to treat wastewater and reduce pollution before discharge.

Focusing on Safety and Alternatives

Of course, nobody wants chemicals in food or water unless there’s a good reason. Oversight groups like the World Health Organization and the FDA study health impacts closely. Proper limits keep sodium metabisulphite at levels proven safe for the vast majority of people. At home, I prefer to check ingredient lists, especially for kids with asthma. Those with allergies need reliable choices and honest packaging. Some food makers turn to alternatives like ascorbic acid (vitamin C) or natural drying to meet consumer demand for cleaner labels.

Better transparency, clear warnings for sensitive individuals, and responsible use offer a path forward. Sodium metabisulphite serves a real purpose in preserving food, keeping drinking water safe, supporting medicine, and protecting wine. Respecting sensitivities calls for honest ingredient lists and educating the public about what lands in food and drink. That’s the balance I look for as both a consumer and parent: safety, trust, and the right to make informed choices.

Is Sodium Metabisulphite safe for consumption?

Straight Talk About a Common Preservative

The name sounds intimidating, but sodium metabisulphite turns up all across the supermarket. It keeps dried fruit chewy, wine clear, and shrimp looking fresh for days. Sulphites make food last longer and look better, which certainly matters if you’re running a restaurant or packing school lunches. Still, a kitchen isn’t a chemistry lab. Folks want peace of mind about what actually goes into their dinner.

Learning from Daily Life and Real Science

Nobody in my family used to read labels until one cousin had a rough reaction after eating at a buffet. Turns out, he’s got asthma and didn’t know about food sensitivities. Doctors figured out he’d eaten grapes treated with sodium metabisulphite. People with asthma, especially children, run into these reactions more than most. Regulating agencies don’t take that lightly. In the U.S., the Food and Drug Administration (FDA) made it a rule to label foods listing sulphites—anything with ten parts per million or more. Europe, Canada, Australia, and plenty of other countries picked up similar practices.

For the rest of us, science says sodium metabisulphite doesn’t cause trouble if you keep intake within accepted daily limits. The Joint FAO/WHO Expert Committee on Food Additives points out an average adult can safely handle up to 0.7 milligrams per kilogram of body weight per day. That’s well above what most folks get from an average diet—even if you like your fruit cups and canned potatoes.

Risks Worth Noticing

Exposure isn’t the same for everyone. If you’ve ever walked through a produce section where dried apricots sit uncovered, you know that sulphur smell lingers. Asthmatics, even those without food allergies, can wind up coughing or dealing with tight lungs after eating sulphite-rich meals. It’s rare, but in serious cases people have landed in the hospital. A tiny fraction of the population actually shows allergy-like symptoms after eating sulphite-containing food—even at low levels. Red, itchy skin and stomach discomfort can throw a wrench into an ordinary day.

Processed foods use sodium metabisulphite for reasons tied to food safety as well. Fruit purees, pickled veggies, and shellfish tend to host harmful microbes. Sulphites keep bacteria and molds at bay. Food waste stays low and prices don’t spiral. Yet, more additives mean more potential for trouble for people with unseen sensitivities.

Better Practices and Smarter Choices

There’s a growing demand for preservative-free snacks among families I know. Home cooks rinse dried fruit, soak beans longer, and stick to frozen seafood over treated shrimp in the display case. Some push for clearer labeling, because packaged foods sometimes bury “contains sulphites” in tiny print. People run food allergy support groups where they swap product info and experiences—turns out, kids with sensitivities often know the ingredient lists better than adults.

Producers stand to gain from making safe alternatives and listing ingredients in plain language. Supermarkets carry more “sulphite-free” snacks every year, and smaller distilleries try traditional, low-sulphite wines for sensitive drinkers. Instead of relying just on chemical shortcuts, keeping food clean and cold during distribution has helped reduce the need for preservatives.

Looking at the Label, Trusting Our Choices

No one wants anxiety in the grocery aisle. For those with health concerns, speaking with doctors, reading labels, and reaching out to manufacturers delivers answers. Sodium metabisulphite’s story reminds us that every bite comes with a choice. Shoppers want control, and clear information lets them keep their place at the table without stress.

What are the health hazards of Sodium Metabisulphite?

What Is Sodium Metabisulphite?

Sodium metabisulphite pops up in a lot of places. Bakers and food manufacturers use it as a preservative, winemakers rely on it as an antioxidant, and some cleaning products contain it as a disinfectant. Some folks might remember its sharp, burnt match smell from old-school photo darkrooms. This chemical sounds useful, but everyone crossing its path deserves to understand what it can do to our bodies.

Breathing Trouble and Asthma Triggers

I’ve learned the hard way that breathing in something you think is harmless can surprise you. A friend working in a wine bottling plant started coughing and wheezing after a few days on the job. The culprit? Sodium metabisulphite fumes mixing with the air. Studies from respected health agencies like the CDC show that inhaling its dust or vapors can inflame the lungs, trigger asthma attacks, or make existing respiratory problems worse. Even people without a history of asthma can end up with breathing difficulties after exposure.

Skin and Eye Irritation

This chemical doesn’t stop at the lungs. Skin contact can cause redness, swelling, and itching. Some workers in food factories develop rashes if the chemical lands on them, especially after repeated exposure. Eyes sting and burn if sodium metabisulphite sneaks into them. In rare cases, severe reactions happen in people sensitive to sulfites. I talked to a chef who broke out in hives every time she cleaned equipment treated with preservatives containing this ingredient.

Food Sensitivities and Allergies

Plenty of processed foods, dried fruits, and even some restaurant dishes include sodium metabisulphite to help them last longer. Problem is, not everyone’s body reacts kindly. People with asthma or a history of allergies should be especially careful. Sulfite-sensitive individuals can develop hives, stomach cramps, and sometimes go into life-threatening anaphylactic shock. The FDA requires food makers to list it on the label if concentrations go above a certain level, but traces can slip in unnoticed. In many parts of the world, food labeling is lagging—leaving sensitive people in danger without ever knowing what set them off.

Potential Harm to Gut Health

Research suggests that sodium metabisulphite may interfere with our gut’s microbial balance. Scientists at the University of Sydney found that sulfite preservatives can inhibit the growth of healthy gut bacteria. This disruption may reduce the body’s ability to absorb nutrients and protect against disease, though much remains to be studied. I’ve seen friends with sensitive stomachs suffer bouts of bloating and digestive upset after eating foods rich in preservatives.

What Can We Do?

There’s a clear need for tougher safety measures. Food producers and industrial users benefit from better training and equipment—simple things like masks, gloves, and improved ventilation keep exposure down. People at home can check product labels and choose fresh or frozen foods without added preservative when possible. Doctors and pharmacists should continue educating folks about what to avoid if they’re at risk. My experience says asking questions about what’s in your food and your workplace supplies helps protect your health. Chemistry helps feed the world, but it only works in our favor when handled with care and respect for its risks.

How should Sodium Metabisulphite be stored?

Why Storage Matters More Than Folks Think

Anyone who has handled chemicals knows storage is more than a backroom detail. With sodium metabisulphite, a little slip can cause big headaches—think pungent smells, surprise fires, and ruined product. I remember working in a food facility where one careless spill damaged an entire pallet of fruit. That wasn’t pretty, and we all learned how easy it is to lose control if the basics get ignored.

Air and Moisture Are the Big Enemies

Sodium metabisulphite pulls in water from the air. Leave a bag open, and it clumps. Over time, that white powder turns yellowish and loses strength. In a bakery where I once helped out, nobody wanted to use lumpy, yellow powder. Not only does it affect quality, but inhaling airborne powder can irritate noses and lungs. Good workers want a safe place, not clouds of strong-smelling dust.

Keep It Cool, Dry, and Tightly Sealed

The best spot for storage is a cool, dry, and well-ventilated area. Basements without moisture control won’t cut it. High humidity or heat invites a chemical reaction with water in the air, producing sulfur dioxide gas. That gas can irritate eyes and throats. Store the powder off the floor, away from pipes that might sweat or drip.

Always seal containers right after use. I’ve seen businesses use thick, screw-top plastic drums or heavy-gauge poly bags—the kind that keeps industrial solvents out. Some facilities double-bag everything, just for peace of mind. Labelling isn’t just paperwork: clear labeling prevents confusion and mistakes, especially for staff grabbing supplies in a hurry.

Don’t Mix With the Wrong Crowd

Chemicals don’t get along with everyone. Sodium metabisulphite reacts badly near acids, strong oxidizers, or flammable materials. Acids release a lung-burning gas. Once, a cleaning crew mixed solutions by mistake after a label fell off, causing an evacuation. Store this powder separately and make sure every container has a solid lid. Staff should keep it apart from bleach, acids, and food that could absorb odors or dust.

Smarter Training, Better Outcomes

Safe storage only works with good habits on the ground. Training goes further than reading a binder. Supervisors should walk new staff through real-life examples and set expectations for labeling, sealing, and regular inspections. Using personal protective equipment like gloves and dust masks cuts down on risk, too.

Regular Checks Keep Things Running Smooth

Conducting routine checks prevents those slow-building problems—like a leaky sack or poor shelving—from turning into bigger incidents. Keep written records to spot patterns, such as humidity spikes or old stock going soft. Digital monitoring now helps some companies spot trouble before a problem grows.

Bottom Line

Storing sodium metabisulphite right protects people and saves money. My work over the years has shown that attention to shelter, climate, labeling, and teamwork turns a risky material into a reliable part of daily operations. Add a culture of respect for chemistry and the workplace stays a whole lot safer for everyone.

Is Sodium Metabisulphite approved for use in food products?

Looking Beyond the Chemical Name

Most people probably haven't thought much about sodium metabisulphite. Its name may sound like it belongs on a laboratory shelf, but this salt crops up in some foods many of us eat. Fruit juices, dried fruit, wine, pickles, and even frozen shrimp sometimes list it among their ingredients. Its job: keep things from getting brown, mushy, or full of bacteria. It extends shelf life and preserves color. For folks in the food business, it solves real headaches. But with any food additive, safety comes under the spotlight. Does it get the green light from regulators?

What the Authorities Say

The U.S. Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA) both allow sodium metabisulphite as a food additive. It even carries official codes—E223 in Europe—showing it passed safety reviews. Regulatory agencies don’t simply rubber stamp chemicals. Scientists study their effects on humans through animal studies, research trials, and toxicology reports before they sign off. The FDA sets strict upper limits, recognizing that people can have sensitivities, especially those with asthma. Labels must declare its presence in packaged foods, offering some protection for sensitive consumers.

Why People Worry

Most of us don’t give preservatives much thought until someone gets sick. Some folks react badly to sulphites, like sodium metabisulphite. Their chests tighten, they break out in hives, or they find it hard to breathe. These reactions aren’t common, but they are real enough that restaurants and food companies should stay alert. My own experience working in a restaurant kitchen showed me how much care goes on behind the scenes with ingredients. Some chefs avoid sulphites in salad bars after hearing from customers who couldn’t tolerate them, even if the product technically remains legal to use. Attention to allergies and sensitivities makes a difference.

Do We Need Preservatives?

Food waste costs families money and damages the environment. Preservatives like sodium metabisulphite slow spoilage. Without them, some foods would either rot before reaching stores, or become home to bacteria. Imagine dried apricots or wine without that sharp, clean taste—we’d lose foods people count on in lunch boxes or kitchens. Governments balance these benefits against risks. Cautious use makes sense, especially if you check labels, pay attention to your own reaction, and buy from reputable producers.

Finding the Right Balance

Preservatives won’t disappear from food production anytime soon. The answer doesn’t lie in banning them altogether; that would mean more food waste, fewer choices, and higher prices. What matters is informed use and keeping safe limits. Regulators could look out for new research and keep reviewing chemicals, warning the public early if new problems turn up. Meanwhile, food makers can explore safe alternatives, use lower amounts when possible, and keep allergy warnings clear and easy to spot. People like me, who read labels carefully and ask questions, can protect themselves. In the end, the story fades into the details on the underside of a food package, but the decisions made affect us every time we fill our grocery baskets.

Sodium Metabisulphite
Names
Preferred IUPAC name sodium oxidooxidosulfate(2−)
Other names Disodium disulfite
Sodium pyrosulfite
Pronunciation /ˌsəʊ.di.əm ˌmɛ.təˈbaɪ.sʌl.faɪt/
Preferred IUPAC name sodium disulfite
Other names Disodium disulfite
Sodium pyrosulfite
Pronunciation /ˌsoʊdiəm ˌmɛtəˈbaɪsʌlfaɪt/
Identifiers
CAS Number 7681-57-4
Beilstein Reference Beilstein Reference 3566770
ChEBI CHEBI:38101
ChEMBL CHEMBL1351
ChemSpider 21514
DrugBank DB09466
ECHA InfoCard 100.972.409
EC Number 231-673-0
Gmelin Reference 78697
KEGG C06735
MeSH D02.241.081.065.178.200
PubChem CID 24846
RTECS number UX8225000
UNII EB6EPC68CY
UN number UN 3077
CompTox Dashboard (EPA) DTXSID2020787
CAS Number 7681-57-4
Beilstein Reference Beilstein Reference: **3537494**
ChEBI CHEBI:38101
ChEMBL CHEMBL1357
ChemSpider 16211021
DrugBank DB14526
ECHA InfoCard 100.028.246
EC Number 231-673-0
Gmelin Reference 63792
KEGG C07347
MeSH D013481
PubChem CID 24406
RTECS number UX8225000
UNII AGG2FN16EV
UN number UN 3077
Properties
Chemical formula Na₂S₂O₅
Molar mass 222.33 g/mol
Appearance White or pale yellow crystalline powder
Odor Pungent
Density 1.48 g/cm³
Solubility in water Soluble in water
log P -3.7
Vapor pressure Negligible
Acidity (pKa) 7
Basicity (pKb) 7.0 (pKb)
Magnetic susceptibility (χ) Diamagnetic
Dipole moment 1.66 D
Chemical formula Na2S2O5
Molar mass 190.107 g/mol
Appearance White or pale yellow crystalline powder
Odor Pungent
Density 1.48 g/cm³
Solubility in water Soluble in water
log P -3.7
Vapor pressure Negligible
Acidity (pKa) 6.0
Basicity (pKb) 7.0
Magnetic susceptibility (χ) Diamagnetic
Refractive index (nD) 1.520
Dipole moment 2.62 D
Thermochemistry
Std molar entropy (S⦵298) 143.3 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -944.2 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -1090.0 kJ/mol
Std molar entropy (S⦵298) 143 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -947 kJ·mol⁻¹
Std enthalpy of combustion (ΔcH⦵298) -947 kJ/mol
Pharmacology
ATC code V03AB02
ATC code A12EP02
Hazards
Main hazards Harmful if swallowed, causes serious eye irritation, may cause respiratory irritation.
GHS labelling GHS05, GHS07
Pictograms GHS05, GHS07
Signal word Warning
Hazard statements Harmful if swallowed. Causes serious eye damage. May cause respiratory irritation.
Precautionary statements P264, P270, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P312, P330, P333+P313, P337+P313, P342+P311, P362+P364, P501
NFPA 704 (fire diamond) 2-0-1-W
Autoignition temperature > 430°C
Lethal dose or concentration LD50 (oral, rat): 1132 mg/kg
LD50 (median dose) 1132 mg/kg (rat, oral)
NIOSH NIOSH: WS5600000
PEL (Permissible) PEL: 5 mg/m³
REL (Recommended) 500 mg/kg
IDLH (Immediate danger) 570 mg/m3
Main hazards Harmful if swallowed; causes serious eye damage; may cause respiratory irritation.
GHS labelling GHS02, GHS05, GHS07
Pictograms GHS05, GHS07
Signal word Warning
Hazard statements Hazard statements: Harmful if swallowed. Causes serious eye damage. May cause respiratory irritation.
Precautionary statements P264, P270, P271, P273, P280, P301+P330+P331, P304+P340, P305+P351+P338, P312, P337+P313, P342+P311, P403+P233, P501
NFPA 704 (fire diamond) '2-0-1-W'
Autoignition temperature > 440°C (824°F)
Lethal dose or concentration LD50 (oral, rat): 1132 mg/kg
LD50 (median dose) LD50 (oral, rat): 1132 mg/kg
NIOSH NIOSH: WS5600000
PEL (Permissible) PEL: 5 mg/m³
REL (Recommended) 200 mg/kg
IDLH (Immediate danger) 230 mg/m³
Related compounds
Related compounds Sodium bisulfite
Sodium sulfite
Sodium thiosulfate
Potassium metabisulfite
Sulfur dioxide
Related compounds Sodium bisulfite
Sodium sulfite
Sodium thiosulfate
Potassium metabisulfite
Sulfur dioxide